دانشگاه شهید مدنی آذربایجان

 آمار

تعداد نشریات5
تعداد شماره‌ها116
تعداد مقالات1,347
تعداد مشاهده مقاله1,352,381
تعداد دریافت فایل اصل مقاله1,293,427
Saghi, Majid, Mahanpoor, Kazem. (1397). Tetracycline and Doxycycline photocatalytic degradation by Nano α-Fe2O3/12-tungstosilicic acid prepared through forced hydrolysis and reflux condensation. , 1(2), 32-53. doi: 10.22049/cic.2018.26341.1022
Majid Saghi; Kazem Mahanpoor. "Tetracycline and Doxycycline photocatalytic degradation by Nano α-Fe2O3/12-tungstosilicic acid prepared through forced hydrolysis and reflux condensation". , 1, 2, 1397, 32-53. doi: 10.22049/cic.2018.26341.1022
Saghi, Majid, Mahanpoor, Kazem. (1397). 'Tetracycline and Doxycycline photocatalytic degradation by Nano α-Fe2O3/12-tungstosilicic acid prepared through forced hydrolysis and reflux condensation', , 1(2), pp. 32-53. doi: 10.22049/cic.2018.26341.1022
Saghi, Majid, Mahanpoor, Kazem. Tetracycline and Doxycycline photocatalytic degradation by Nano α-Fe2O3/12-tungstosilicic acid prepared through forced hydrolysis and reflux condensation. , 1397; 1(2): 32-53. doi: 10.22049/cic.2018.26341.1022

Tetracycline and Doxycycline photocatalytic degradation by Nano α-Fe2O3/12-tungstosilicic acid prepared through forced hydrolysis and reflux condensation

Communications In Catalysis
مقاله 4، دوره 1، شماره 2، اسفند 2018، صفحه 32-53    اصل مقاله (1.55 M)
نوع مقاله: Original Article
شناسه دیجیتال (DOI): 10.22049/cic.2018.26341.1022
نویسندگان
Majid Saghi؛ Kazem Mahanpoor*
Department of Chemistry, Arak branch, Islamic Azad University, Arak, Iran
چکیده
I
In the research, spherical α-Fe2O3 nanoparticles (NPs) were synthesized and supported on the surface of 12-tungstosilicic acid (12-TSA.7H2O) using forced hydrolysis and reflux condensation (FHRC) method. Photocatalytic activity of pure and supported α-Fe2O3 NPs (α-Fe2O3/2-TSA.7H2O) for Tetracycline (TC) and Doxycycline (DC) degradation was investigated using UV/H2O2 process. The products were characterized by FTIR, SEM/EDX, BET surface area and XRD. The experiments were designed considering four variables including pH, the initial concentration of pollutant, catalyst concentration and H2O2 concentration at two-levels and three central point's using full factorial experimental design. The results indicated that supporting α-Fe2O3 NPs caused to improve the filtration, recovery and photocatalytic activity of NPs.Under optimal conditions, 88.44% TC and 87.67% DC were degraded following 50 and 120 min, respectively. The results indicated that reactions follows first-order kinetic and rate coefficient for TC and DC degradation reactions equals to 0.0178 and 0.0074 min–1, respectively.
کلیدواژه‌ها
Tetracycline؛ Doxycycline؛ Full factorial؛ α-Fe2O3؛ α-Keggin
آمار
تعداد مشاهده مقاله: 785
تعداد دریافت فایل اصل مقاله: 789


سامانه مدیریت نشریات علمی. قدرت گرفته از سیناوب