Synthesis, Structural Properties and Water Oxidation Activity of Iron (III) Complexes with Salophen Ligands

Shaghaghi, Zohreh; Tajdar, Habibeh; Aligholivand, Mehri

doi:10.22049/cic.2024.29382.1035

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	Synthesis, Structural Properties and Water Oxidation Activity of Iron (III) Complexes with Salophen Ligands
Communications In Catalysis
دوره 2، شماره 2، فروردین 2024، صفحه 8-21 اصل مقاله (717.48 K)
نوع مقاله: Original Article
شناسه دیجیتال (DOI): 10.22049/cic.2024.29382.1035
نویسندگان
Zohreh Shaghaghi^* ؛ Habibeh Tajdar؛ Mehri Aligholivand
Coordination Chemistry Research Laboratory, Department of Chemistry, Faculty of Science, Azarbaijan Shahid Madani University,5375171379, Tabriz, Iran
چکیده
In this work, FeIII salophen complexes 1-3 were prepared from the reaction of H2L1-3 (H2L1=N,N'-bis(salicylidene)-4-chloro-1,2-phenylenediamine, H2L2=N,N'-bis(salicylidene)-4-bromo-1,2-phenylenediamine, and H2L3=N,N'-bis(salicylene)-4-nitro-1,2-phenylenediamine) with FeCl3.6H2O. The structure of the complexes was investigated by spectroscopic techniques, molar conductivity measurements and elemental analysis. In addition, water oxidation activity of complexes was investigated by different electrochemical methods in alkaline solution. The results showed that the compounds reveal high performance for water oxidation in terms of overpotential and Tafel slope values. FeIII complex 3 displayed the best activity for the reaction with low overpotential of 485 mV at a j of 10 mA cm-2 and a suitable Tafel slope of 216 mV dec-1 among other complexes. This is due to larger electrochemically active surface area of 3, which leads to more active catalytic sites and improved water oxidation activity. Finally, the chronoamperometry test revealed that 3 is a stable and durable electrocatalyst for water oxidation.
کلیدواژه‌ها
Iron(III) complexes؛ Salophen-type ligands؛ Electrocatalysts؛ Electrochemistry؛ Water oxidation

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Synthesis, Structural Properties and Water Oxidation Activity of Iron (III) Complexes with Salophen Ligands